Fabrication of polymeric 3D structure containing metal/metal oxide nanoparticles by two-photon processes

Xuan-Ming Duan; Hong-Bo Sun; Koshiro Kaneko; Satoshi Kawata

doi:10.1117/12.505406

3 November 2003 Fabrication of polymeric 3D structure containing metal/metal oxide nanoparticles by two-photon processes

Xuan-Ming Duan, Hong-Bo Sun, Koshiro Kaneko, Satoshi Kawata

Author Affiliations +

Proceedings Volume 5211, Nonlinear Optical Transmission and Multiphoton Processes in Organics; (2003) https://doi.org/10.1117/12.505406
Event: Optical Science and Technology, SPIE's 48th Annual Meeting, 2003, San Diego, California, United States

Abstract

The two-photon polymerizations of metal ions doped acrylate monomers and oligomers have been investigated, which has been applied for three-dimensional (3-D) micro/nano-structure fabrication. Titanium (IV) ions doped urethane acrylate photopolymerisable resins were synthesized, and their properties of optical and polymerization were investigated. The resolution of two-photon polymerization for micro/nanofabrication was evaluated. Titanium oxide (TiO₂) nanoparticles were generated in the polymer matrix of micro-sized polymer structures. A 3-D diamond photonic crystal structure, which consisted of polymer composite materials of TiO₂ nanoparticles, was successfully fabricated by direct laser writing technique, and its photonic bandgap was confirmed. This work would give us a new solution for producing 3-D micro/nanodevices of functional polymer composite materials.

Citation Download Citation

Xuan-Ming Duan, Hong-Bo Sun, Koshiro Kaneko, and Satoshi Kawata "Fabrication of polymeric 3D structure containing metal/metal oxide nanoparticles by two-photon processes", Proc. SPIE 5211, Nonlinear Optical Transmission and Multiphoton Processes in Organics, (3 November 2003); https://doi.org/10.1117/12.505406

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