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Nano gold particles interact strongly with visible light to excite the collaborative oscillation of conductive electrons within nano particles resulting in a surface plasmon resonance which makes them useful for various applications including bio-labeling. In this paper, we study the effect of particle sizes with particle plasmon resonant wavelength and the coupling between pair of elliptical metallic disks and ellipsoid particles by simulations and experiments. The red-shift resonant peak wavelength of coupled particles to that of single particle is due to particle plasmons near-field coupling. The shift decays is approximately exponentially with increasing particle spacing, and reaches zero when the gap between the two particles exceeds about 2.5 times the particle short axis length. It is also found that the exponential decay of peak shift with particle gap is size independent but shape dependent.
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Kai-Hung Su, Qi-Huo Wei, Xiang Zhang, Jack J. Mock, David R. Smith, Sheldon Schultz, "Optical properties of coupled nano gold particles," Proc. SPIE 5221, Plasmonics: Metallic Nanostructures and Their Optical Properties, (28 October 2003); https://doi.org/10.1117/12.506371