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27 February 2004 Polarizability functions of the N2 and O2 molecules
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Proceedings Volume 5396, Tenth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics. Part I: Radiation Propagation in the Atmosphere and Ocean; (2004) https://doi.org/10.1117/12.548210
Event: Tenth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics, 2003, Tomsk, Russian Federation
Abstract
The semiempirical method for calculation of the polarizability functions for diatomic homonuclear molecules as piecewise-continuous ones has been developed. The polarizability functions found exhibit physically correct asymptotic behaviour at small and large internuclear separations and agree with the polarizability functions near the nuclear equilibrium position of the molecule. In the framework of the approach the exchange interactions have been considered to improve the polarizability functions under large internuclear distances including the range of small overlapping of the electronic shells of the interacting atoms. The method has been applied to calculate the polarizability functions of the N2 and O2 molecules in the internuclear distances Rε[0,∞).
© (2004) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Michail A. Buldakov and Victor N. Cherepanov "Polarizability functions of the N2 and O2 molecules", Proc. SPIE 5396, Tenth Joint International Symposium on Atmospheric and Ocean Optics/Atmospheric Physics. Part I: Radiation Propagation in the Atmosphere and Ocean, (27 February 2004); https://doi.org/10.1117/12.548210
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