12 June 2006 Structural study of ZrO2 and HfO2 thin films grown by atomic layer deposition
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Proceedings Volume 5946, Optical Materials and Applications; 59460E (2006) https://doi.org/10.1117/12.639159
Event: Optical Materials and Applications, 2005, Tartu, Estonia
Raman spectroscopy (RS), x-ray dimaction (XRD), and reflection high-energy electron diffraction (RHEED) were applied for a structural analysis of ZrO2 and HfO2 thin films grown on Si substrates by chloride atomic layer deposition (ALD). The RS measurements were performed on freestanding ZrO2 and HfO2 films. In these conditions, high-quality micro-Raman spectra of 100-660-nm-thick films were obtained in the whole range of interest, 80-800cm-1. The structural data determined by RS were complemented by the XRD and RHEED data. As a result, it has been ascertained that at the initial stage of the ALD growth of ZrO2 and HfO2 films at 500 and 600 °C, respectively, metastable phases form and dominate. In the case of ZrO2 films, this phase has been identified as the tetragonal polymorph. Over the film thickness range of 56-660 nm, the absolute amount of the tetragonal ZrO2 has been shown to be almost constant, with its relative amount decreasing and the amount of the monoclinic phase increasing when the film thickness increases. Neither RS nor XRD allowed any unambiguous identification of the metastable phase in the otherwise monoclinic HfO2 films. According to the RHEED data, at the very initial stage of the HfO2 growth, cubic HfO2 is present.
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Ahti Niilisk, Ahti Niilisk, Jaan Aarik, Jaan Aarik, Teet Uustare, Teet Uustare, Hugo Mändar, Hugo Mändar, Sergey Tkachev, Sergey Tkachev, Murli Manghnani, Murli Manghnani, } "Structural study of ZrO2 and HfO2 thin films grown by atomic layer deposition", Proc. SPIE 5946, Optical Materials and Applications, 59460E (12 June 2006); doi: 10.1117/12.639159; https://doi.org/10.1117/12.639159

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