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We report here thermal and non linear optics measurements: Photoinduced Second Harmonic Generation (PISHG) and Two Photon Absorption (TPA) measurements in the skutterudite RFe4Sb12 (R=Ce,La) and Ce0.7Fe3.5Ni0.5Sb12. The results show existence of important signal in LaFe4Sb12 compared to the CeFe4Sb12. At the same time the third-order Two-Photon Absorption (TPA) possesses maximums at low temperature. The introduction of Ni into the CeFe4Sb12 materials decreases clearly the PISHG and TPA signal.
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K. Nouneh, S. Benet, I. Kityk, R. Viennois, S. Charar, B. Claudet, "Thermal properties and nonlinear optics of skutterudites," Proc. SPIE 5949, Nonlinear Optics Applications, 59491U (5 October 2005); https://doi.org/10.1117/12.624606