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10 May 2006 Synthesis, characterization, and differentiation of high energy amine peroxides by MS and vibrational microscopy
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Abstract
Synthesis and characterization of hexamethelene triperoxide diamine (HMTD), tetramethylene diperoxide dicarbamide (TMDD) and tetramethylene diperoxide acetamide (TMDA) using GC-MS, HPLC-MS, FT-IR and Raman Microscopy has been carried out. The study also centered in the synthesis and characterization of other cyclic amine peroxides, including and different forms of caged peroxides from other diaminoalkanes. Interest also was given to the secondary products of all syntheses and the effect of temperature in the composition mixtures of the preparations. Differentiation spectroscopy and spectrometry studies were also conducted. In these studies the differences in the ν(O-O), ν(N-C), ν(N-H), ν(C-O), δ(CH3-C) and δ(C-O) bands for Raman and IR were established. For the GC/MS spectrometric studies retention times and fragmentation patterns for GC-MS and GC-FT-IR useful in amine peroxide differentiation were also established.
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Alvaro J. Peña-Quevedo, Nairmen Mina-Calmide, Nelmary Rodríguez, Deborah Nieves, Robert B. Cody, and Samuel P. Hernández-Rivera "Synthesis, characterization, and differentiation of high energy amine peroxides by MS and vibrational microscopy", Proc. SPIE 6201, Sensors, and Command, Control, Communications, and Intelligence (C3I) Technologies for Homeland Security and Homeland Defense V, 62012E (10 May 2006); https://doi.org/10.1117/12.666202
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