Optimizing specific third-order polarizabilities and approaching the fundamental limit in donor substituted cyanoethynylethene (CEE) molecules

Joshua C. May; Philip R. LaPorta; Bweh Esembeson; Ivan Biaggio; Tsuyoshi Michinobu; Filip Bures; François Diederich

doi:10.1117/12.682451

7 September 2006 Optimizing specific third-order polarizabilities and approaching the fundamental limit in donor substituted cyanoethynylethene (CEE) molecules

Joshua C. May, Philip R. LaPorta, Bweh Esembeson, Ivan Biaggio, Tsuyoshi Michinobu, Filip Bures, François Diederich

Author Affiliations +

Proceedings Volume 6331, Linear and Nonlinear Optics of Organic Materials VI; 633101 (2006) https://doi.org/10.1117/12.682451
Event: SPIE Optics + Photonics, 2006, San Diego, California, United States

Abstract

We review the molecular third-order polarizability of a series of compact two-dimensional cyanoethynylethene derivatives and show that the best molecules have a nonlinearity that is only by a factor of 50 lower than the fundamental limit derived by Kuzyk, which is revealed to be a quite useful concept in discussing the observed trends in molecular nonlinearities. We also show that the nonlinearity of this family of molecules contains a large two-photon contribution, and that the best molecules have a very high specific third-order polarizability, meaning that they pack a large nonlinearity in a relatively small size.

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Joshua C. May, Philip R. LaPorta, Bweh Esembeson, Ivan Biaggio, Tsuyoshi Michinobu, Filip Bures, and François Diederich "Optimizing specific third-order polarizabilities and approaching the fundamental limit in donor substituted cyanoethynylethene (CEE) molecules", Proc. SPIE 6331, Linear and Nonlinear Optics of Organic Materials VI, 633101 (7 September 2006); https://doi.org/10.1117/12.682451

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