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13 June 2008 Thermal and optical properties of SiO2-Al2O3-PbF2-ZnF2-ZnO-LaF3-Nd2O3 glasses
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Proceedings Volume 7120, Optical Fibers and Their Applications 2008; 71200G (2008) https://doi.org/10.1117/12.804518
Event: Optical Fibers and Their Applications 2008, 2008, Bialowieza, Poland
Abstract
The investigation of crystallization kinetics of oxyfluoride glass 37SiO2 - 10Al2O3 - 43PbF2 - 4,5ZnF2 - 0,2LaF3 - 5,3ZnO - 0,5Nd2O3 using differential scanning calorimeter were presented. Thermal analysis were performed by using Friedman and Ozawa - Flynn - Wall methods. Reaction rate and activation energy of the crystallization process as function of reaction progress were calculated on the base of DSC measurements performed with heating rates 5, 10, 15oC/min. Glass ceramic oxyfluoride matrix were formed by thermal treatment of as melted glasses. Obtained glass-ceramic structure showed higher level of emission and less FWHM of luminescence band compared to as melted glass.
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Dominik Dorosz and Marcin Kochanowicz "Thermal and optical properties of SiO2-Al2O3-PbF2-ZnF2-ZnO-LaF3-Nd2O3 glasses", Proc. SPIE 7120, Optical Fibers and Their Applications 2008, 71200G (13 June 2008); doi: 10.1117/12.804518; https://doi.org/10.1117/12.804518
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