Paper
17 May 2010 New nonlinear Gd1-xRxCa4O(BO3)3 (R = Lu, Sc) crystals for 400-nm blue-violet light generation by type-I noncritical phase-matching frequency doubling processes
Lucian Gheorghe, Alexandru Achim, Pascal Loiseau, Gerard Aka
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Abstract
Single crystals of Gd1-xRxCa4O(BO3)3 (R3+ = Sc3+ or Lu3+) with large size and good quality have been grown by Czochralski method. The optical birefringence of Gd1-xScxCa4O(BO3)3 and Gd1-xLuxCa4O(BO3)3 crystals can be controlled by changing the compositional parameter x. The chemical compositions of the grown crystals were determined and X-ray diffraction measurements have been carried out to characterize the structural changes with compositional parameter x. According to our assumptions, the obtained results demonstrate that two of the grown crystals convert the near-infrared radiation of 800nm into blue-violet light (400nm) by type-I noncritical phase-matching (NCPM) second-harmonic generation (SHG) processes along Y axis.
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Lucian Gheorghe, Alexandru Achim, Pascal Loiseau, and Gerard Aka "New nonlinear Gd1-xRxCa4O(BO3)3 (R = Lu, Sc) crystals for 400-nm blue-violet light generation by type-I noncritical phase-matching frequency doubling processes", Proc. SPIE 7469, ROMOPTO 2009: Ninth Conference on Optics: Micro- to Nanophotonics II, 746904 (17 May 2010); https://doi.org/10.1117/12.859049
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KEYWORDS
Crystals

Second-harmonic generation

Nonlinear crystals

Ions

Lutetium

Laser crystals

Polishing

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