16 April 2011 SUEX process optimization for ultra-thick high-aspect ratio LIGA imaging
Author Affiliations +
Proceedings Volume 7972, Advances in Resist Materials and Processing Technology XXVIII; 79722U (2011); doi: 10.1117/12.882872
Event: SPIE Advanced Lithography, 2011, San Jose, California, United States
Abstract
The focus of this paper is on the use of SUEX Thick Dry Film Sheet (TDFS) laminates which DJ DevCorp is developing as a thick resist material in optical and X-ray lithography. Preliminary thick dry film sheets up to 1mm thickness were successfully prepared and patterned at the CAMD X-ray beamlines and presented at HARMST 2007. Recently, new results have been published using SUEX resist sheets in UV lithography showing great market potential including plating molds for metal microparts, polymer MEMS, multilayer microfluidics structures, BioMEMS, medical devices, wafer level packaging processes, and displays. The SUEX TDFS are available in a range of thicknesses from 100μm to 1mm or more and are pre-cut into a number of standard wafer sizes. This new material is a modified epoxy formulation containing an antimony-free photo acid generator (PAG) prepared under a highly controlled solvent-less process which provides uniform coatings between two throw-away layers of protective polyester film. As part of our initial studies resist layers of 250, 500 and 1000μm were laminated onto regular silicon wafers using a hot roll laminator at a speed of 1ft/min at 75°C. The entire substrate preparation takes about 1 hour and with practice users can prepare up to 10 substrates in this time which are typically ready to use within 2 hours. In our efforts to develop a commercially viable product we have conducted experiments using standard equipment available at CAMD (Quintel UV aligner and CAMD XRLM 1 and 4 beamline). Initial X-ray exposure tests were done with a bottom dose ranging between 100 and 400 J/cm3 and a top/bottom dose ratio of less than 3 for sheets up to 2mm in thickness. Exposure time for typical conditions of the CAMD storage ring (ring current ranging between 100 and 160mA, beam lifetime of about 10hrs at 100mA ring current) is about 10-15min for a 4' wafer. After exposure the samples were immediately post exposure baked between 70°C and 110°C using a convection oven, taken out and cooled to RT then relaxed up to 3 days before development to reduce stress. Development was done in PGMEA for up to 3 hours for the 1000μm thick samples followed by a short IPA rinse and drying in air. Very high aspect ratios of 100 or more have been routinely patterned with nearly perfectly straight sidewalls (~1-1.5μm deviation for a 1mm tall structure) and excellent image fidelity.
© (2011) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
Donald W. Johnson, Jost Goettert, Varshni Singh, Dawit Yemane, "SUEX process optimization for ultra-thick high-aspect ratio LIGA imaging", Proc. SPIE 7972, Advances in Resist Materials and Processing Technology XXVIII, 79722U (16 April 2011); doi: 10.1117/12.882872; https://doi.org/10.1117/12.882872
PROCEEDINGS
14 PAGES


SHARE
KEYWORDS
Semiconducting wafers

Silicon

X-rays

Photomasks

Photoresist processing

Plating

Skin

RELATED CONTENT

SNR200 chemically amplified resist optimization
Proceedings of SPIE (July 07 1997)
X-ray mask fabrication process
Proceedings of SPIE (July 03 1995)
Electroplated nickel mold insert for LIGA
Proceedings of SPIE (September 19 1995)
Development of a low cost x ray mask for high...
Proceedings of SPIE (July 20 1998)
B-Si masks for storage ring X-ray lithography
Proceedings of SPIE (March 19 1984)

Back to Top