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28 November 2011Laser ablation mechanism of transparent layers on semiconductors with ultrashort laser pulses
Transparent dielectric layers on semiconductors are used as anti-reflection coatings both for photovoltaic applications
and for mid-infrared optical elements. We have shown recently that selective ablation of such layers is possible using
ultrashort laser pulses at wavelengths being absorbed by the semiconductor. To get a deeper understanding of the
ablation mechanism, we have done ablation experiments for different transparent materials, in particular SiO2 and SixNy
on silicon, using a broad range of wavelengths ranging from UV to IR, and pulse durations between 50 and 2000 fs. The
characterization of the ablated regions was done by light microscopy and atomic force microscopy (AFM). Utilizing
laser wavelengths above the silicon band gap, selective ablation of the dielectric layer without noticeable damage of the
opened silicon surface is possible. In contrast, ultrashort pulses (1-2 ps) at mid-infrared wavelengths already cause
damage in the silicon at lower intensities than in the dielectric layer, even when a vibrational resonance (e.g. at λ = 9.26
μm for SiO2) is addressed. The physical processes behind this, on the first glance counterintuitive, observation will be
discussed.
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Tino Rublack, Stefan Hartnauer, Michael Mergner, Markus Muchow, Gerhard Seifert, "Laser ablation mechanism of transparent layers on semiconductors with ultrashort laser pulses," Proc. SPIE 8190, Laser-Induced Damage in Optical Materials: 2011, 81901Z (28 November 2011); https://doi.org/10.1117/12.899066