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22 February 2012 Exciton formation in dye doped OLEDs using electrically detected magnetic resonance
Augusto Batagin-Neto, Jorge A Gómez, Fernando A Castro, Frank Nüesch, Libero Zuppiroli, Carlos F. O. Graeff
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Proceedings Volume 8333, Photonics and Optoelectronics Meetings (POEM) 2011: Optoelectronic Devices and Integration; 83331B (2012) https://doi.org/10.1117/12.918246
Event: Photonics and Optoelectronics Meetings 2011, 2011, Wuhan, China
Abstract
Electrically Detected Magnetic Resonance (EDMR) was used to investigate the influence of dye doping molecules on spin-dependent exciton formation in Aluminum (III) 8-hydroxyquinoline (Alq3) based OLEDs with different device structures and temperature ranges. 4-(dicyanomethylene)-2-methyl-6-{2-[(4-diphenylamino-phenyl]ethyl}-4H-pyran (DCM-TPA) and 5,6,11,12-tetraphenylnaphthacene (Rubrene) were used as dopants. A strong temperature dependence have been observed for doped OLEDs, with a decrease of two orders of magnitude in EDMR signal for temperatures above ~200 K. The signal temperature dependence were fitted supposing different spin-lattice relaxation processes. The results suggest that thermally activated vibrations of dopants molecules induce spin pair dissociation, reducing the signal.
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Augusto Batagin-Neto, Jorge A Gómez, Fernando A Castro, Frank Nüesch, Libero Zuppiroli, and Carlos F. O. Graeff "Exciton formation in dye doped OLEDs using electrically detected magnetic resonance", Proc. SPIE 8333, Photonics and Optoelectronics Meetings (POEM) 2011: Optoelectronic Devices and Integration, 83331B (22 February 2012); https://doi.org/10.1117/12.918246
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KEYWORDS
Organic light emitting diodes
Excitons
Molecules
Magnetism
Magnetic sensors
Doping
Signal processing
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