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Sponsored and Published by SPIE Volume 9455 The papers included in this volume were part of the technical conference cited on the cover and title page. Papers were selected and subject to review by the editors and conference program committee. Some conference presentations may not be available for publication. The papers published in these proceedings reflect the work and thoughts of the authors and are published herein as submitted. The publisher is not responsible for the validity of the information or for any outcomes resulting from reliance thereon. Please use the following format to cite material from this book: Author(s), “Title of Paper,” in Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing XVI, edited by Augustus W. Fountain III, Proceedings of SPIE Vol. 9455 (SPIE, Bellingham, WA, 2015) Article CID Number. ISSN: 0277-786X ISBN: 9781628415711 Published by SPIE P.O. Box 10, Bellingham, Washington 98227-0010 USA Telephone +1 360 676 3290 (Pacific Time)· Fax +1 360 647 1445 Copyright © 2015, Society of Photo-Optical Instrumentation Engineers. Copying of material in this book for internal or personal use, or for the internal or personal use of specific clients, beyond the fair use provisions granted by the U.S. Copyright Law is authorized by SPIE subject to payment of copying fees. The Transactional Reporting Service base fee for this volume is $18.00 per article (or portion thereof), which should be paid directly to the Copyright Clearance Center (CCC), 222 Rosewood Drive, Danvers, MA 01923. Payment may also be made electronically through CCC Online at copyright.com. Other copying for republication, resale, advertising or promotion, or any form of systematic or multiple reproduction of any material in this book is prohibited except with permission in writing from the publisher. The CCC fee code is 0277-786X/15/$18.00. Printed in the United States of America. Publication of record for individual papers is online in the SPIE Digital Library. Paper Numbering: Proceedings of SPIE follow an e-First publication model, with papers published first online and then in print. Papers are published as they are submitted and meet publication criteria. A unique citation identifier (CID) number is assigned to each article at the time of the first publication. Utilization of CIDs allows articles to be fully citable as soon as they are published online, and connects the same identifier to all online, print, and electronic versions of the publication. SPIE uses a six-digit CID article numbering system in which:
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Conference CommitteeSymposium Chair Symposium Co-chair Conference Chair Conference Program Committee
Session Chairs
IntroductionPerhaps it was providence, or just good timing, that the 100th Anniversary of the first use of industrialized gases occurred in the middle of the 16th meeting of the CBRNE Sensing Conference: part of the 2015 SPIE Defense, Security + Sensing Symposium. Despite the continued restrictions on travel and conference attendance, primarily from government participants, the CBRNE Conference was well attended and provided a unique forum where novel chemical and explosives sensing, bio-detection, and nuclear and radiological detection technologies and methods were presented over three days. This year several themes emerged that define some of the most interesting presentations:
Smartphones are proving a popular platform for hand-held spectroscopy. Smartphone cameras developed for producing high pixel-count images and operating under low-light conditions have proven sufficient for: fluorescence microscopy, colorimetric spectroscopy of colored liquids in enzyme linked immunosorbent assays, and aerosol particle counting. The use of a smartphonebased platform provides substantial usability benefits including advanced user-interface and data-processing algorithms, and services such as cloud storage, geographic information system-tagging, and remote expert analysis. New rationally-designed materials to improve chemical detection were described, but they were not all equally promising. In one of the best presentations, Dr. Otto Muskens provided a very informative talk on the use of plasmonics for the enhancement of electromagnetic fields around metallic nanostructures and demonstrated surface-enhanced infrared spectroscopy using arrays of indium tin oxide plasmonic nanoantennas. The combination of label-free infrared spectroscopy with the versatility of doped metal oxides has the potential of opening up new applications in sensing and spectroscopy, for example, as multifunctional transparent electrodes, catalysts, or electrically or optically controllable plasmonic devices. Similarly, several inherently complex, multi-pulse spectroscopic techniques were highlighted and show enormous potential for enhanced sensitivity and interference rejection. Multiplex Coherent Anti-Stokes Raman spectroscopy (MCARS) has been used to create a complete Raman spectrum of a material of interest in milliseconds. However, these MCARS spectra often embedded in a nonresonant background (NRB) that reduces the ability to use those spectra to positively identify the material of interest. ARL presented several algorithms for NRB removal. However, a subsequent MCARS presentation by Dr. Paul Pellegrino indicated that MCARS is an inherently difficult technique and that is not quite ready for prime time analysis of unknowns. Once again I want to thank my committee who really makes this conference happen. There is no way I could review all the abstracts and proceedings papers or host all the sessions without them. I am confident that this conference remains the most important means of bringing together the leaders in the field of CBRNE sensing from every sector; government, academia and industry. I am already excited about next year’s conference and the new developments it will report on. Augustus W. Fountain III |