7 March 2016 Ultra-sensitive near-infrared fiber-optic gas sensors enhanced by metal-organic frameworks
Author Affiliations +
We demonstrate ultra-sensitive near-infrared (NIR) fiber-optic gas sensors enhanced by metalorganic framework (MOF) Cu-BTC (BTC=benzene-1,3,5- tricarboxylate), which is coated on a single-mode optical fiber. For the first time, we obtained high-resolution NIR spectroscopy of CO2 adsorbed in MOF without seeing any rotational side band. Real-time measurement showed different response time depending on the concentration of CO2, which is attributed to the complex adsorption and desorption mechanism of CO2 in Cu-BTC. The lowest detection limit of CO2 we achieved is 20 ppm with only 5-cm long Cu-BTC film.
Conference Presentation
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Xinyuan Chong, Xinyuan Chong, Ki-Joong Kim, Ki-Joong Kim, Erwen Li, Erwen Li, Yujing Zhang, Yujing Zhang, Paul R. Ohodnicki, Paul R. Ohodnicki, Chih-Hung Chang, Chih-Hung Chang, Alan X. Wang, Alan X. Wang, "Ultra-sensitive near-infrared fiber-optic gas sensors enhanced by metal-organic frameworks", Proc. SPIE 9702, Optical Fibers and Sensors for Medical Diagnostics and Treatment Applications XVI, 970207 (7 March 2016); doi: 10.1117/12.2214021; https://doi.org/10.1117/12.2214021

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