Energy harvesting has been gaining significant interest as a potential solution for energizing next generation sensor and energy storage devices. The most widely investigated material for piezoelectric and pyro-electric energy harvesting to date is PZT (Lead Zirconate Titanate), owing to its good piezoelectric and pyro-electric properties. However, Lead is detrimental to human health and to the environment. Hence, alternative materials are required to be investigated for this purpose. In this paper, a lead free material Lithium Niobate (LNB) is reported as a potential material for pyro-electric energy harvesting. Although, it has lower pyro-electric properties than PZT, it has better properties than other lead free alternatives of PZT such as ZnO. In addition, LNB has a high curie point of 1142 °C, which makes it suitable for high temperature environment where other pyro-electric materials are not suitable. Therefore, a single crystal LNB has been investigated as a source of energy harvesting under alternative heating and cooling environment. A commercial 0.2 F super-capacitor was used as the energy storage device.