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We have established that film morphology and laser induced heating from dye absorption are important parameters in the creation of new photonastic materials. Photonastic is defined as regular, repeatable movement in a pre-programmed direction following exposure to light. This work builds upon the development of photonastic polymers of ruthenium sulfoxide complexes, where the action of bending is ascribed to phototriggered isomerization of a sulfoxide ligand in a ruthenium coordination complex that is covalently attached to polynorbornene. The bending is analyzed in terms of a bilayer cantilever model.
Jeffrey J. Rack,Maksim Y. Livshits, andJisoo Shin
"Photonastic effects in ruthenium sulfoxide polymers", Proc. SPIE 9939, Light Manipulating Organic Materials and Devices III, 993909 (23 September 2016); https://doi.org/10.1117/12.2237391
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Jeffrey J. Rack, Maksim Y. Livshits, Jisoo Shin, "Photonastic effects in ruthenium sulfoxide polymers," Proc. SPIE 9939, Light Manipulating Organic Materials and Devices III, 993909 (23 September 2016); https://doi.org/10.1117/12.2237391