Self-assembly provides a powerful approach for fabricating metasurfaces using bespoke colloidal nanocrystals (NCs) whose sizes, shapes, and surface chemistry can be rationally designed to achieve complex, heterogeneous, and hierarchical photonic architectures. I will present our group’s work in the area of NC assembly for plasmonic metasurfaces, where shaped metal NCs serve as the building blocks for resonant optical nanojunctions. We have demonstrated that metal NCs can be assembled into large-scale periodic arrays using interfacial assembly, or into more exquisite architectures (e.g. chains, lattices) using entropy-driven steric forces. Uniquely, these metal NCs possess single-crystalline surfaces with low roughness that enable the generation of low-loss structures that support phenomena such as intense electromagnetic field localization, non-linear optical response, and inelastic electron tunneling.
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