Robert E. Simpson,1 Nur Qalishah Adanan,2 Yunzheng Wang,3 Thomas Knight,1 Zhaogang Dong4
1Univ. of Birmingham (United Kingdom) 2Singapore Univ. of Technology and Design (Singapore) 3Shandong Univ. (China) 4A*STAR Institute of Materials Research and Engineering (Singapore)
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I will introduce two very different chalcogenide thin films that exhibit plasmonic or plasmonic-like behaviour in the visible spectrum. The first film is elemental tellurium and we argue that this plasmonic-like behaviour is due to partially delocalised p-orbital electrons that are readily polarized at frequencies in the visible spectrum.The Te films can support surface plasmon polariton-like modes and Te nanodiscs can support local surface plasmon resonances.We believe these results might pave the way for elemental Te-programmable photonics.
I will also show how chalcogenide films can be used to grow silver nanoparticles over large areas. In particular, I will show how co-depositing Sb2S3 with Ag results in a perfect absorber material consiting of self-organised nanoresonators. We call this material Black Silver, and we have used it to detect femtomolar concentrations of streptavidin.
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Robert E. Simpson, Nur Qalishah Adanan, Yunzheng Wang, Thomas Knight, Zhaogang Dong, "Chalcogenide plasmonic-like materials," Proc. SPIE PC13111, Plasmonics: Design, Materials, Fabrication, Characterization, and Applications XXII, PC131110L (3 October 2024); https://doi.org/10.1117/12.3028868