28 August 2017 Ultrathin extreme ultraviolet patterning stack using polymer brush as an adhesion promotion layer
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Abstract
Initial readiness of extreme ultraviolet (EUV) patterning has been demonstrated at the 7-nm device node with the focus now shifting to driving the “effective” k1 factor and enabling the second generation of EUV patterning. In current EUV lithography, photoresist thicknesses <30  nm are required to meet resolution targets and mitigate pattern collapse. Etch budgets necessitate the reduction of underlayer thickness as well. Typical spin-on underlayers show high defectivity when reducing thickness to match thinner resist. Inorganic deposited underlayers are lower in defectivity and can potentially enable ultrathin EUV patterning stacks. However, poor resist-inorganic underlayer adhesion severely limits their use. Existing adhesion promotion techniques are found to be either ineffective or negatively affect the etch budget. Using a grafted polymer brush adhesion layer, we demonstrate an ultrathin EUV patterning stack comprised of inorganic underlayer, polymer brush, and resist. We show printing of sub-36-nm pitch features with a good lithography process window and low defectivity on various inorganic substrates, with significant improvement over existing adhesion promotion techniques. We systematically study the effect of brush composition, molecular weight, and deposition time/temperature to optimize grafting and adhesion. We also show process feasibility and extendibility through pattern transfer from the resist into typical back end stacks.
© 2017 Society of Photo-Optical Instrumentation Engineers (SPIE)
Indira Seshadri, Indira Seshadri, Anuja De Silva, Anuja De Silva, Luciana Meli, Luciana Meli, Chi-Chun Charlie Liu, Chi-Chun Charlie Liu, Cheng Chi, Cheng Chi, Jing Guo, Jing Guo, Hoa D. Truong, Hoa D. Truong, Kristin Schmidt, Kristin Schmidt, John C. Arnold, John C. Arnold, Nelson M. Felix, Nelson M. Felix, Lovejeet Singh, Lovejeet Singh, Tsuyoshi Furukawa, Tsuyoshi Furukawa, Ramakrishnan Ayothi, Ramakrishnan Ayothi, Angelique Raley, Angelique Raley, Richard A. Farrell, Richard A. Farrell, } "Ultrathin extreme ultraviolet patterning stack using polymer brush as an adhesion promotion layer," Journal of Micro/Nanolithography, MEMS, and MOEMS 16(3), 033506 (28 August 2017). https://doi.org/10.1117/1.JMM.16.3.033506 . Submission: Received: 26 April 2017; Accepted: 25 July 2017
Received: 26 April 2017; Accepted: 25 July 2017; Published: 28 August 2017
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