In a recent article, La Spada et al.1 considered an electrically small particle made of an isotropic dielectric material of permittivity embedded in an isotropic host material of permittivity . It was stated in Ref. 1 that “that the polarizability of an arbitrary shaped particle can be expressed as2) in Ref. 1 further reinforces the scalar natures of the depolarization factor and the polarizability without any preconditions on the shape of the particle and the orientation of an electric field incident on it.
However, the reader should note that the polarizability of an electrically small particle of an isotropic dielectric material embedded in an isotropic host material cannot be a scalar unless the particle is either spherical or cubical. The polarizability of an arbitrarily shaped particle has to be a dyadic (or, equivalently, a second-rank tensor), because depolarization cannot be represented by a scalar . Therefore, Eq. (1) in Ref. 1 does not have the correct structure for an electrically small particle of arbitrary shape.
The foregoing is illustrated by the polarizability of an ellipsoidal particle being correctly represented as the dyadic2 For more general ellipsoidal shapes, expressions for in terms of elliptic functions were published in 1945 by Osborn3 and Stoner.4 In fact, integral equation-based formulations of the polarizability dyadic are now available for the general case of a bianisotropic ellipsoidal particle embedded in a bianisotropic host material5 based on the corresponding depolarization dyadic.6
La Spada et al. also derived expressions for the absorption and scattering cross-sections of an ellipsoidal particle, after explicitly confining themselves to the case of the incident electric field being parallel to the longest of the three principal axes of the particle. In that special case, one diagonal component of the polarizability dyadic alone is indeed sufficient, but that specialization cannot reduce the polarizability dyadic to a scalar, because the polarizability dyadic does not depend on the direction of the incident electric field.
L. La SpadaR. IovineL. Vegni, “Electromagnetic modeling of ellipsoidal nanoparticles for sensing applications,” Opt. Eng. 52(5), 051205 (2013).OPEGAR0091-3286http://dx.doi.org/10.1117/1.OE.52.5.051205Google Scholar
E. C. Stoner, “The demagnetizing factors for ellipsoids,” Philos. Mag. 36(263), 803–821 (1945).PMHABF1478-6435Google Scholar
W. S. WeiglhoferA. LakhtakiaB. Michel, “Maxwell Garnett and Bruggeman formalisms for a particulate composite with bianisotropic host medium,” Microwave Opt. Technol. Lett. 15(4), 263–266 (1997). Erratum 22(3), 221 (1999).MOTLEO0895-2477http://dx.doi.org/10.1002/(ISSN)1098-2760Google Scholar
B. MichelW. S. Weiglhofer, “Pointwise singularity of dyadic Green function in a general bianisotropic medium,” Arch. Elektron. Übertrag. 51(3), 219–223 (1997). Erratum 52(1), 31 (1998).Google Scholar