Light-field cameras are gaining attention for their unique light gathering and post-capture processing capabilities. In our previous work, we combined light-field imaging with structured light technology to realize three-dimensional (3D) reconstruction for highly reflective surface. However, due to the lack of effective calibration of the light-field camera and reconstruction systems, it cannot meet the requirements of precise 3D measurement. A universal sub-aperture image extraction algorithm for the light-field camera with hexagonal microlens is presented to accurately extract the multidirectional images. Then, we explore the spatial relationship in equivalent camera array (ECA) of focused light-field camera according to the perspective variation of sub-aperture images. After that, an accurate 3D measurement system based on ECA model is proposed to achieve 3D measurement for highly reflective surface. To test the system’s practical performance, a precision analysis is conducted for a standard gauge block with ground truth. By comparing the reconstruction result of traditional method and ours, we demonstrated the validity of the proposed method to perform 3D measurement for highly reflective surface.