We present a novel two-photon 3D printing approach based on a dedicated resist chamber in which we apply a quasi-static electric field with variable orientation and amplitude during the 3D printing process. This allows aligning the director of not yet polymerized liquid-crystal elastomer resist. After two-photon exposure, the alignment is “frozen” in the polymerized voxel. For the next voxel, the electric field vector can be changed, etc. In this manner, we can 3D print hetero-microstructures of liquid-crystal elastomers. We envision applications under ambient conditions where mechanical actuation is induced by temperature variation or by focused light.
Recently, we introduced an optical cavity in the infrared fingerprint spectral region for enhanced sensing of chiral molecules within the cavity (Phys. Rev. Lett. 124, 033201 (2020)). Here, we discuss a simplified version of this cavity in which one of the formerly two silicon disk arrays is replaced by a homogenous, unstructured thin silicon film. We show that CD enhancement factors exceeding 100 are still possible, while the line shape of the resonances changes. Furthermore, we investigate the reduction of the CD enhancement versus molecule density due to non-helicity preserving interaction of light with the molecules in the cavity.
This presentation was first delivered at Optics + Photonics on 12 August 2019 and has been included as part of this Digital Forum to enable scholarly dialogue. Please use the original citation when citing:
Proceedings Volume 11080, Metamaterials, Metadevices, and Metasystems 2019; 110800S (2019) https://doi.org/10.1117/12.2530087
The sensing of chiral molecules is important for chemical, pharmaceutical, and medical applications. The determination of the relative concentration of the two molecular mirror versions (enantiomers) in a given mixture is of particular importance for several reasons, in particular because the two enantiomers can have very different biological effects. This task can be achieved by circular dichroism (CD), the normalized difference between the absorption of incident left- and right-handed circularly polarized light. The molecular CD signal is typically weak, and many different kinds of nanostructures have been proposed for enhancing it. Most of them provide local enhancements only in electromagnetically small near-field regions attached to the material structures, resulting in vanishing total enhancements when experimentally meaningful analyte volumes are considered. In this talk, I will present the design of a cavity composed of two parallel arrays of silicon disks that allows to enhance the total CD signal by more than two orders of magnitude for a given molecule concentration and given thickness of the cell containing the molecules. I will show that the underlying principle is helicity-preserving first-order diffraction into helicity-preserving modes with large transverse momentum and long lifetimes. In sharp contrast, in a conventional Fabry-Perot cavity, each reflection flips the handedness of light, leading to large intensity enhancements inside the cavity, yet to smaller CD signals than without the cavity.
The sensing of chiral molecules is important for chemical, pharmaceutical, and medical applications. The fast and accurate testing of small quantities of analyte by optical means is desirable, in particular for lab-on-a-chip technologies. Different nanostructures have been proposed for enhancing the molecular circular dichroism (CD) in their near fields, yet not all structures and near fields serve this purpose equally well. We will present the design guidelines that lead to nanostructures that enhance the CD signal of molecular solutions, use these guidelines for optimizing arrays of silicon disks, and demonstrate a more than tenfold increase in sensitivity.