The absorption spectrum of monodeuterated water, HDO has been investigated between 11200 and 12400 cm-1. The spectrum has been recorded using IFS-125M interferometer with spectral resolution of 0.05 cm-1. For measurements White’s-type cell were used. The bright light emitting diode (LED) EDEI-1LS3-R was applied as a source of radiation. Signal to noise ratio was about 104. The spectral line parameters - line positions, intensities and half-widths were obtained by least square fitting. As a result of the spectrum analysis the line list containing more than 1500 lines was created. The spectral line parameters have been compared with the previous measured and calculated data.
Measurements of water vapor absorption spectra in the visible spectral region near 0.44 mkm are performed using FTspectrometer IFS-125M and Light-emitting diode (LED) as source of radiation. Water vapor spectrum has been obtained by averaging over 17136 scans recorded at 34,8 m optical path length, temperature 24 ± 1 С and pressure of sample 24,8 mBar. Due to strong emission of LED source it was possible to achieve signal-to-noise ratio about 104 and to record weak lines with intensities of 6 10-27 cm/molecule. Comparisons with results of early works are made.
The report presents a description of properties of published data on spectral lines parameters of deuterated isotopologues of hydrogen sulfide - HDS, HD34S, D2S, D234S. Properties values characterizing data quality are calculated taking into account the validity criteria and credit estimation according to publishing criteria. Formalized criteria of data check based on the constraints and selection rules known from the vibrational-rotational theory, as well as an expert evaluation are utilized for validation of the original experimental transitions and energy levels. The consistent and accurate set of the vibration - rotation (VR) energy levels is derived based on the cleaned transitions. Published vibrational-rotational transitions and energy levels of considered molecules as well as the knowledge base are available in the Internet in W@DIS information system (IS).
In this paper we present the results of Н216О absorption spectrum investigation recorded by a high resolution Fouriertransform spectrometer IFS-125M in the region 15500 – 16000 cm-1. Absorption path of 34.8 m and resolution of 0.03 см-1 were chosen to record the spectrum. White type multipass absorption cell with a basic length of 60 cm were used. Light-emitting diode (LED) was applied as a source of radiation. Signal-to-noise ratio is about 104, making it possible to measure parameters of lines with intensity up to 2*10-27 cm/molecule. Least-square-fitting algorithm was used to retrieve of the spectroscopic parameters from measured spectral data set. Spectral line positions and line intensities derived from the fitting were compared to data obtained in previous works.