In recent years, the ability to pattern large areas at the micro- and nano-scale with stimuli-responsive materials has opened the opportunity to engineer surface structures and trigger peculiar properties such as complex optical functionalities or surface properties by laser-matter interactions. The use of light-sensitive materials, such as azobenzene compounds, can open the opportunity to active manipulate in terms of morphology, physical and mechanical properties a pre-patterned architectures, which are intrinsically static once fabricated.
We employ azopolymers, in which the rapid and reversible photoisomerization reaction of azobenzene molecules can actuate mass transport phenomena typically parallel to the light polarization. The azopolymeric film is patterned by soft-imprinting as an array of micro-holes showing a well-defined isotropic round pores. Upon a linearly polarized illumination (365 nm, 150 W/cm2), we observe a deformation of the initial holes along the polarization direction, in such a way that the circular pores are transformed into long closed slits. A rotation of the polarization by 90° triggers a reconfiguration of the pristine round shape, with a good degree of control of the photo-induced pore reshaping. Due to the polarized-directionality of the photo-manipulation we demonstrate the possibility to tune the pristine morphology and properties along specific directions, providing a smart engineered platform with different reshaped micro-patterns. The light-induced contraction and expansion reshaping strategy of a porous polymeric structures shows exciting potential for a number of applications including microfluidics, lithography and tissue engineering. Tuning cells behavior in response to material manipulation cues is a promising goal in biology
In this work we investigate new degrees of freedom in controlling the physical properties of structured photo-sensitive materials that can be usefully exploited in many application fields. We employ azopolymers, a class of light responsive materials, which are structured in micro-pillar array. A reversible and controlled change in morphology of a pre-patterned polymeric film under properly polarized illumination is demonstrated to provide the opportunity to engineer surface structures and dynamically tune their properties. We exploit the laser process taking advantage of the light-induced deformation of a micro-textured azopolymeric film in order to modify the surface hydrophobicity along specific direction.
We propose a liquid polymeric compound based on photo-responsive azo-polymers to be used as light-activated optical element with tunable and reversible functionalities. The interaction of a laser beam locally modifies the liquid density thus producing a refractive index gradient. The laser induced refractive index profiles are observed along the optical axis of the microscope to evaluate the total phase shift induced and along the orthogonal direction to provide the axial distribution of the refractive index variation. The focusing and imaging properties of the liquid lenses as functions of the light intensity are illustrated.
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