Time-varying media have recently emerged as a new paradigm for wave manipulation. In this talk we provide a discussion of the recent progress achieved with photonic metamaterials whose properties stem from their modulation in time. We review the basic concepts underpinning temporal switching and its relationship with spatial scattering, and deploy the resulting insight to review photonic time-crystals and their emergent research avenues such as topological and non-Hermitian physics. We then extend our discussion to account for spatiotemporal modulation and its applications to nonreciprocity, synthetic motion, giant anisotropy, amplification and other effects. Finally, we conclude with a review of the most attractive experimental avenues recently demonstrated, and provide a few perspectives on emerging trends for future implementations of time-modulation in photonics.
I will report on a switchable time-varying mirror, composed of an ITO-Au stack, which can be efficiently modulated in time, by a driving ultrafast laser pulse, with over a ten-fold increase in reflectivity and a bandwidth increase of the reflected pulse to 31 THz. This temporal response is unbounded by the pump pulse bandwidth and originates from the shortening of the response time of the mirror beyond saturation. Moreover, I will show the dissipative self-organisation of programmable random lasers from the reversible out-of-equilibrium self-assembly of colloids. They can thus reconfigure and cooperate by emulating the ever-evolving spatiotemporal relationship between structure and functionality typical of living matter.
Time-varying media have recently emerged as a new paradigm for wave manipulation, due to the synergy between the discovery of highly nonlinear materials, such as epsilon-near-zero materials, and the quest for wave applications, such as magnet-free nonreciprocity, multimode light shaping, and ultrafast switching. In this review, we provide a comprehensive discussion of the recent progress achieved with photonic metamaterials whose properties stem from their modulation in time. We review the basic concepts underpinning temporal switching and its relation with spatial scattering and deploy the resulting insight to review photonic time-crystals and their emergent research avenues, such as topological and non-Hermitian physics. We then extend our discussion to account for spatiotemporal modulation and its applications to nonreciprocity, synthetic motion, giant anisotropy, amplification, and many other effects. Finally, we conclude with a review of the most attractive experimental avenues recently demonstrated and provide a few perspectives on emerging trends for future implementations of time-modulation in photonics.
Time-varying metasurfaces have recently emerged as a new topic of interest for control of light at the nanoscale and exploration of fundamental physics. We demonstrate time diffraction from a time slit in an unstructured metasurface. In a pump-probe experiment, excitation of the Berreman mode of a thin film of Indium-Tin-Oxide over gold leads to strong, efficient all-optical modulation of the film, and to time diffraction of the probe. In comparison to previous works in unstructured epsilon-near-zero films, we obtain a 6 nm frequency shift and a 23 nm broadening using lower intensities and a significantly lower thickness of 40 nm, which demonstrates the minimal footprint of the structure. The deeply subwavelength nature of the sample makes a time-varying interpretation simple and efficient, paving the way for time-dependent architectures for ultrafast optical experiments.
Here we will review our current activities on the realization of photonic active structures based on biomaterials. Nanofibers of DNA incorporating light-emitting chromophores are reported with enhanced optical emission and lasing properties tailorable by the fiber size and architecture. The research leading to these results has received funding the European Research Council (ERC) under the European Union’s Horizon 2020 research and innovation programme (grant agreement No. 682157, “xPRINT”) and from the Italian Minister of University and Research through the PRIN 201795SBA3 project.
Introducing thin, light-weight and high efficiency photovoltaics will make solar cells more suitable to be integrated in urban landscapes or even small gadgets and would largely contribute to solving the global warming threat that we are facing today. Stacking of solar cells with different characteristic bandgaps is the most common strategy to surpass the Shockley-Queisser efficiency limit, but such tandem devices are typically heavy weight, rigid and costly. Thinning down of absorber materials is a good strategy to overcome these restrictions. However, nano- and micro-meter thicknesses come down to the expense of light absorption. An effective approach to tackle the absorption problem in thin materials is nanopatterning the absorbing layer.
In this work we introduce hyperuniform designs as an effective way to control scattered light into particular range of angles (revealed as a ring in k-space of the reflected/transmitted light), with the aim to efficiently trap light in μm-thick Silicon (Si) cells. We first consider the –theoretical and experimental- case of a single Si solar cell, and thanks to an optimization algorithm, we show the highest light absorption in 1 μm-thick Si film to date. We also compare different designs for best anti-reflection effect on top of light trapping and characterize the increased absorption in photoelectrochemical devices. Second, we incorporate a similar light trapping strategy in a tandem solar cell, by using a periodic GaAs nanowire array as a top cell. We introduce two waveguiding effects in GaAs NW-Si thin film architectures to explain the 4-fold light absorption in the Si ultrathin bottom cell for tailored geometries of the NW array. These results represent significant light trapping scheme that is obtained “for free” when using a nanostructured top cell.
The understanding of the phenomena underlying the interaction of photons with dielectric, metallic and hybrid microand nano-structures and the development of advanced fabrication tools have paved the way to the realization of complex, nanostructured photonic structures, with tailored and exotic absorption and emission properties. Among such nanostructured materials, polymer nanofibers have intriguing and specific properties: they can embed molecular and quantum dot light sources, they can transport light among distant emitters and they can be arranged in 2-dimensional and 3-dimensional architectures in a controlled fashion, forming complex networks of interacting light emitters. However, coupling of light with polymer nanofibers depends on many variables, being often limited by the arrangement and positioning of the nanoscale light-sources, and by the fiber geometry. Here we report on the fabrication of active polymer nanofibers with improved surface properties and controlled geometry by electrospinning. Polarization and momentum spectroscopy of light emitted by molecular compounds and single quantum dots embedded in electrospun polymer fibers, evidence that efficient, nanostructured photon sources with targeted polarization and coupling efficiency can be realized in nanofiber-based photonic environments.
We report on optical analogues of well-known electronic phenomena such as Bloch oscillations and electrical Zener breakdown. We describe and detail the experimental observation of Bloch oscillations and resonant Zener tunneling of light waves in static and time-resolved transmission measurements performed on optical superlattices. Optical superlattices are formed by one-dimensional photonic structures (coupled microcavities) of high optical quality and are specifically designed to represent a tilted photonic crystal band. In the tilted bands condition the miniband of degenerate cavity modes turns into an optical Wannier-Stark ladder (WSL). This allows an ultrashort light pulse to bounce between the tilted photonic band edges and hence to perform Bloch oscillations, the period of which is defined by the frequency separation of the WSL states. When the superlattice is designed such that two minibands are formed within the stop band, at a critical value of the tilt of photonic bands the two WSLs couple within the superlattice structure. This results in a formation of a resonant tunneling channel in the minigap region, where the light transmission boosts from 0.3% to over 43%. The latter case describes the resonant Zener tunneling of light waves.
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