The improving of the technology related to the Spatial Light Modulators (SLM), which can be used to modulate the wavefront of a light beam in many different applications in Optics and Photonics, has widespread their use in many new ways. In particular, the continue miniaturization of the pixel size let them be used as a master for Diffractive Optical Elements(DOE) recording applications. One of these displays isthe parallel-addressed liquid crystal on silicon (PA-LCoS) microdisplay, which offers easily the possibility of phase-only modulation without coupled amplitude modulation, but can be use also as an amplitude master just rotating the angles of two polarizers. Together with the DOEs, the optic recording material is also one of the crucial componentsin the system. Photoresist has been used classically for this purpose. Recently some works provide results of the incorporation of photopolymers, initially used for holographic recording, to fabricate DOEs. Among photopolymers, polyvinil alcohol/acrylamide (PVA/AA) materials have been studied firstly due to the accurate control of their optical properties and the ease of fabrication. Nevertheless, this kind of photopolymer presents a high level of toxicity due mainly to the monomer, acrylamide. In this sense, we made efforts to search alternative “green” photopolymers, one of these is called “Biophotopol”. This material presents good optical properties; although, it has two principal drawbacks: its refractive index modulation is lower than the PVA/AA one and the dye used presents very low absorption at 532 nm. In order to solve these problems for recording spherical diffractive lenses, in the present work we have explored different possibilities. On the first place, we have modified the fabrication technique of the solid layer to achieve thicker samples, on the second place, we have introduced a biocompatible crosslinker monomer. These two actions provide us a higher value of the phase modulation capability. On the third place, we have modified the dye to record DOE’s with the wavelength of 532 nm and obtain a direct comparison with the results obtained with PVA/AA materials.
There is an increasing demand for new holographic recording materials. One of them are photopolymers, which are becoming a classic media in this field. Their versatility is well known and new possibilities are being created by including new components, such as nanoparticles or dispersed liquid crystal molecules in classical formulations, making them interesting for additional applications in which the thin film preparation and the structural modification have a fundamental importance. Prior to obtaining a wide commercialization of displays based on photopolymers, one of the key aspects is to achieve a complete characterization of them. In this sense, one of the main parameters to estimate and control is the shrinkage of these materials. The volume variations change the angular response of the hologram in two aspects, the angular selectivity and the maximum diffraction efficiency. One criteria for the recording material to be used in a holographic data storage application is the shrinkage, maximum of 0.5%. Along this work, we compare two different methods to measure the holographic recording material shrinkage. The first one is measuring the angle of propagation for both diffracted orders ±1 when slanted gratings are recorded, so that an accurate value of the grating vector can be calculated. The second one is based on interference measurements at zero spatial frequency limit. We calculate the shrinkage for three different photopolymers: a polyvinyl alcohol acrylamide (PVA/AA) based photopolymer, one of the greenest photopolymers whose patent belongs to the Alicante University called Biophotopol and on the last place a holographic-dispersed liquid crystal photopolymer (H-PDLC).
Multiplexed diffraction gratings were recorded in 300 μm thick layers of Biophotopol photopolymer by using peristrophic multiplexing schema. Thirteen sinusoidal phase gratings were stored in a low toxicity recording medium. The diffraction efficiency conservation of the multiplexed diffraction efficiency obtained was studied along the time.
We introduce a polyvinil alcohol/acrylamide (PVA/AA) photopolymer compound in a holographic memory testing
platform to provide experimental results for storage and retrieval of information. We also investigate different
codification schemes for the data pages addressed onto the parallel-addressed liquid crystal on silicon (PA-LCoS) device,
used as the data pager, such as binary intensity modulation (BIM), and hybrid-ternary modulation (HTM), and we will
see that an actual approximation for HTM can be obtained with a PA-LCoS device. We will also evaluate the effect of
the time fluctuations in the PA-LCoS microdisplays onto the BIM and HTM regimes. Good results in terms of signal-tonoise
ratio and bit-error ratio are provided with the experimental system and using the PVA/AA photopolymer produced
in our lab, thus showing its potential and interest for future research focused on this material with highly tunable
Photopolymers are classical holographic recording materials. Recently their chemical composition and the
fabrication techniques have been optimized for many new applications such as interconnectors, solar concentrations,
2-D photonic structures, or wave-guides. Their potential usefulness has been drastically increased by the
introduction of dispersed liquid crystal molecules; these components can be concentrated in the non-exposed zones
of the material by a photopolymerization induced phase separation process (PIPS). Therefore, by combining
polymer and dispersed liquid crystal (PDLC) has emerged as a new composite material for switchable diffractive
optical elements (DOEs). Parallel to the material advances some techniques have been proposed to record very low
spatial frequencies DOE’s. Different researchers have reported proposes to record DOE like fork gratings, photonics
structures, lenses, sinusoidal, blazed or fork gratings. In this work we have studied the behavior of a PDLC material
to record DOE’s with different spatial periods: from 1 μm, using holographic technique, to more than 200 μm,
Liquid Cristal on Silicon (LCoS) display working in mostly amplitude mode as a master. Due to the improvement in
the spatial light modulation technology and the pixel miniaturization, this technique permits us store gratings with
spatial frequencies until few microns. Additionally, this technology permits us an accurate and dynamic control of
the phase and the amplitude of the recording beam. In particular, for our case, to generate the blazed gratings, we
use an LCoS-Pluto provided by Holoeye with a resolution of 1920x1080 (HDTV) pixels and a pixel size of 7.7x7.7
Photopolymers are optical recording materials appealing for many different applications such as holography, data storage, interconnectors, solar concentrations, or wave-guides fabrication. Recently the capacity of photopolymers to record diffractive optical elements (DOE’s) has been investigated. Different authors have reported proposes to record DOE like fork gratings, photonics structures, lenses, sinusoidal, blazed or fork gratings. In these experiments there are different experimental set-ups and different photopolymers. In this work due to the improvement in the spatial light modulation technology together with the photopolymer science we propose a recording experimental system of DOE using a Liquid Cristal based on Silicon (LCoS) display as a master to store complex DOE like cylindrical lenses. This technology permits us an accurate control of the phase and the amplitude of the recording beam, with a very small pixel size. The main advantage of this display is that permit us to modify the DOE automatically, we use the software of the LCoS to send the voltage to each pixel In this work we use a photopolymer composed by acrylamide (AA) as polymerizable monomer and polyvinyl alcohol (PVA). We use a coverplated and index matched photopolymer to avoid the influence of the thickness variation on the transmitted light. In order to reproduce the material behaviour during polymerization, we have designed our model to simulate cylindrical lenses and used Fresnel propagation to simulate the light propagation through the DOE and analyze the focal plane and the properties of the recorded lenses.
One of the most promising phase optical recording mediums are photopolymers. In these materials, the use of an index matching component permits a better conservation of the stored information and, additionally, the study of the molecules migration and shrinkage/swelling phenomena separately. In general, the transmitted beam has the information of the thickness and refractive index modulation mixed. Therefore, we propose the introduction of a coverplate besides with an index matching liquid in order to improve the characterization and the conservation. The index matching techniques have been classically used for holographic recording materials. In principle, to obtain an accurate index matching we have to choose a liquid with refractive index very close to the mean of the polymer one. Then, when shrinkage takes place during recording, mainly due to the polymerization, the liquid will fill up the generated grooves minimizing the diffractive effects produced by the relief structure. In fact, in this work we study different index matching components for different photopolymers. The photopolymers analyzed in this work have a polyvinyl alcohol (PVA) as a binder and two different main monomers: one has acrylamide and the other one sodium acrylate. We have recorded very low diffractive gratings and studied their conservation for different index matching components.