With the developing of wearable electronics and information society, integrated energy storage devices are urgently demanded to be integrated on flexible substrates. We successfully demonstrated using direct laser-reduction of the hydrated GO and chloroauric acid (HAuCl4) nanocomposite to fabricate in-plane micro-supercapacitors (MSCs) with fast ion diffusion on paper. The electrode conductivity of these flexible nanocomposites reaches up to 1.1 x 106 S m-1, which enhances superior rate capability of micro-supercapacitors, and large specific capacitances of 0.77 mF cm-2 (17.2 F cm-3 for volumetric capacitance) at 1 V s-1, and 0.46 mF cm-2 (10.2 F cm-3) at 100 V s-1. We also have demonstrated that pulsed laser irradiation rapidly converts the polyimide (PI) sheets into an electrically conductive porous carbon structure in ambient conditions. The specific capacitance of single layer surface supercapacitors can reach 20.4 mF/cm2 at 0.1 mA/cm2 discharge current density. Furthermore, we successfully fabricate the multi-layer supercapacitor with the PI substrate using 3D femtosecond laser direct writing, and the specific capacitances of three layers supercapacitors is 37.5 mF/cm2.
A femtosecond (fs) laser beam machining method has been proposed to improve the quality of micromachining. At first, the coated silica sheet is prepared by pulsed laser deposition, then the coated silica is processed by the fs laser. After that, the aluminum film on a fused silica sheet is cleared out by hydrochloric acid (HCl) in a solution of 10%, and then the microhole array is formed on the silica which has better morphologies. Additionally, some mathematical models are constructed to analyze the diffusion of vapors and reflection of shock waves during the machining process. The theoretical results show that the aluminum film can effectively decrease the pressure gradient of the vapors and the reflection of shock wave pressure on the fused silica during the machining process. The simulation is consistent with experimental results. Finally, coating with a film or not has a great influence on the quality of micromachining, but the types of coating films have little influence. In a word, it is an excellent choice to improve the quality of fs laser processing by coating with a film on a fused silica sheet.
Random laser actions in a disordered media based on ethylene glycol doped with Rh6G dye and Au nanorods have been
demonstrated. It was observed that the size of Au nanorods strongly affects the pump threshold. The experiment results
suggesting that the random lasing properties are dominated by the surface plasmons.
Femtosecond laser micropatterning of silicon with nanometric surface modulation is demonstrated by irradiating through a diffracting pinhole. The irradiation results obtained at fluences above the melting threshold are characterized by optical and scanning electron microscopy and reveal a good agreement with Fresnel diffraction theory. LIPSS have been generated in the micropatterning surface. We found Ripples spacing were found of 550-680 nm. Based on the Sipe and Drude model, the theoretical period of LIPSS is closer to experimental measurements. Due to the diffraction, the LIPPS having a different period appear in a diffraction micropatterning.