In this contribution, we use spectrally resolved and quantitative photoluminescence measurements to parse voltage losses in CdSeTe films and finished devices. We show that sub-bandgap features, in part due to arsenic doping, are responsible for a significant decrease in the thermodynamic voltage limit Voc,ideal. Nevertheless, thanks to excellent material quality and interface passivation, the internal voltage iVoc (i.e., quasi-Fermi-level splitting with QFLS=q×iVoc) of finished devices approaches 1000 mV, in agreement with the high minority-carrier lifetimes measured. The selectivity of the device, and in particular of the back hole contact, is thus the main limitation in these devices.
We report luminescent solar concentrators designs using two-dimensional photonic crystal slabs as light trapping waveguides, resulting in high concentration factors. In all designs, we can achieve luminophore light trapping efficiency above 90%, leading to concentration factors as high as 100.
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