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Modeling of strong laser radiation interaction with objects under the conditions of surface air blow
This spectrochemical analysis was possible for Al, Cu, and Fe alloys objects for both lasers, and in case of composites only if the samples were irradiated by short laser pulse since in the experiment with the long pulse, all composite materials spectra, in general, were very similar to each other – they imitated a grey/black body spectra. For metal alloys in experiments with a short laser pulse only atomic spectra were observed while for long microsecond laser pulses molecular transitions have been registered for Al alloys.
Electron temperatures of plasma created on different materials for short and long laser pulses were found on the base of Boltzmann plots. Temperatures are clearly higher for plasmas generated with a short laser pulse which results from much higher laser power density on the sample surface for short pulse and not from fluence which is 20-40 times larger for long pulse.
Variations of the target’s surface reflection coefficient, caused by the interaction of short pre-pulses with high power density were determined. The experiments were performed using a standard Nd:YAG laser with amplifiers, generating output pulses whose duration amounted to 10 ns and energy to 1 J, with near Gaussian profile.
Laser induced breakdown spectroscopy (LIBS) was used to analyze the emission spectra of targets under the conditions of the interaction of destructive strong and weak as well as long and short excitation laser pulses. A decay of the spectra in the UV range from 200 to around 350 nm was observed when irradiating the target with a long, quasi-cw destructive pulse. Moreover, in the case of an Al target, some AlO molecular spectra appeared, suggesting a chemical reaction of the aluminum atoms with oxygen.
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