Bidirectional reflectance distribution function (BRDF) offers complete description of the spectral and spatial characteristics of opaque materials. The polarized BRDF contains more information, especially for the painted objects and target recognition. In this letter, we measured the in plane polarized spectral BRDF for the steel E235B in the wavelength range of 450-600 nm. The reliability of our results is verified by comparing the experimental data of polytetrafluoroethylene with the reference data. The measuring results indicates that the wavelength of incident light has a positive effect on the BRDF near the specular direction, and has a negative influence for other direction. BRDF increases slowly with reflected zenith angle and decreases rapidly with peak occurs at specular direction, which may be attributed to the shadowing effect. In addition, the results presents that the polarization of incident light has a slight influence on the BRDF of the sample.