8 June 2017 Displacement Talbot lithography: an alternative technique to fabricate nanostructured metamaterials
Author Affiliations +
Abstract
Nanostructured materials are essential for many recent electronic, magnetic and optical devices. Lithography is the most common step used to fabricate organized and well calibrated nanostructures. However, feature sizes less than 200 nm usually require access to deep ultraviolet photolithography, e-beam lithography or soft lithography (nanoimprinting), which are either expensive, have low-throughput or are sensitive to defects. Low-cost, high-throughput and low-defect-density techniques are therefore of interest for the fabrication of nanostructures. In this study, we investigate the potential of displacement Talbot lithography for the fabrication of specific structures of interest within plasmonic and metamaterial research fields. We demonstrate that nanodash arrays and ‘fishnet’-like structures can be fabricated by using a double exposure of two different linear grating phase masks. Feature sizes can be tuned by varying the exposure doses. Such lithography has been used to fabricate metallic ‘fishnet’-like structures using a lift-off technique. This proof of principle paves the way to a low-cost, high-throughput, defect-free and large-scale technique for the fabrication of structures that could be useful for metamaterial and plasmonic metasurfaces. With the development of deep ultraviolet displacement Talbot lithography, the feature dimensions could be pushed lower and used for the fabrication of optical metamaterials in the visible range.
Le Boulbar, Chausse, Lis, and Shields: Displacement Talbot lithography: an alternative technique to fabricate nanostructured metamaterials

INTRODUCTION

Artificially nanostructured materials with novel electromagnetic and optical properties, currently referred as metamaterials, are being extensively researched due to their extraordinary properties. Arrays of holes with a small periodicity, dashes and “fishnet” structures have been widely investigated and are of great interest within plasmonic and metamaterial research fields. These type of structures have been used to fabricate plasmonic metasurfaces that enable waveplates 1,2, linear-to-circular polarization converters 3, helicity-preserving omnidirectional mirrors 4, and for biosensing applications 57. Multilayer metal-dielectric-metal metamaterials based on these structures have been used to generate second or third harmonic wavelengths using their non-linear properties 811 and create negative-index metamaterials (NIMs) from arrays of dashes 12 and fishnets 1315.

Most of the early studies have used e-beam lithography or a focused ion beam in order to fabricate, develop and investigate the properties of these new materials. The fabrication of metamaterials at NIR or visible optical wavelengths requires small periodicities of 600 nm down to 300 nm and feature sizes of 200 to sub-100 nm. This typical feature size for infrared and visible range metamaterials is smaller than the resolution of conventional photolithography and requires a nanofabrication process with 100 or sub-100 nm resolution. High precision, high throughput and low cost manufacturing of such optical NIMs is therefore challenging due to the low dimensions that are required. Since the early research stage and first demonstration of these NIMs structures by different groups in 2005-2006 1315, many groups have successfully demonstrated large-area fabrication processes. Fabrication of large-area fishnet structures has been realized using a wide range of techniques 16, like deep-UV lithography 17,18, nanoimprint lithography 19,20 and interference lithography 2,21.

Recently, a new lithography technique, taking advantage of the Talbot effect, has shown that high-resolution sub-micron patterns can be achieved by moving the sample position through one Talbot period 22,23. The conventional Talbot effect occurs when a periodic mask is illuminated by a plane-wave. The three-dimensional interference pattern created below the mask is called Talbot carpet. Although this effect has been known since 1836, its low depth-of-field has meant that it has not been used for practical applications in semiconductor technology, especially for submicron features. A new method, called Displacement Talbot Lithography (DTL) and commercialized by Eulitha, unlocks the use of the Talbot effect and offers non-contact wafer-scale fabrication of periodic patterns of sub-micron features. Displacement Talbot lithography, using a 375 nm source, and hence conventional i-line resists, allows the fabrication of linear gratings with submicron structure and periodicities as low as 250 nm, owing to the doubling of the mask period frequency for linear gratings 22. Smaller feature sizes are possible with the recent development of systems with a deep UV source (λ=266 nm) 23. For linear gratings, one of the main features of DTL is that the frequency of the mask will be doubled on the wafer, i.e. using a 800 nm period linear grating mask will produce a 400 nm linear grating on the wafer. A second feature is the ability to control the size of the feature on the wafer through varying the exposure dose.

In this article, the potential of displacement Talbot lithography to fabricate nanostructures such as metallic nanodashes and ‘fishnet’ like structures from different linear gratings will be explored. (400 nm, and 600 nm) by using a double exposure process. Two different grating masks, perpendicular to each other, are used to expose sequentially a single photoresist-covered sample prior to development. The capability of the DTL process will be demonstrated and compared with a model in order to explain the tunability of the resist linewidth that the DTL offers, taking the 400 nm linear gratings as an example. The fabrication of dashes and fishnet structures in photoresist and the range of dimensions that one can obtain by varying the exposure dose will be demonstrated and discussed. Finally, the lift-off process used to obtain metallic fishnets of various dimensions will be shown.

1.

EXPERIMENTAL SECTION

An HSQ spin-on-glass layer (Hydrogen silsesquioxane, DOW Corning XR-1541) was spun on a 50 mm silicon (100) wafer to obtain a layer thickness of 120 nm. The layer was baked on a hot plate at 450°C for 10 minutes. A bottom antireflective layer (BARC) (Brewer science - Wide 8C) was spun on top of the HSQ layer to obtain a layer thickness of 90 nm. The layer was baked on a hot plate for 1 min at 80°C and 1 min at 210°C. A 250 nm layer of high contrast positive resist (Dow® Ultra-i 123 diluted with Dow® EC11 solvent) was spun on top of the BARC and cured at 90°C for 90 sec. For the negative resist, a layer of 350 nm (AZ® 15 NXT diluted with AZ® Edge Bead Remover (EBR) solvent with a 7:12 ratio by weight) was spun on top of the BARC and cured at 110°C for 45 sec.

PhableR (Eulitha) Displacement Talbot lithography equipment was used to expose the resist 22,24. The gap between the mask and the wafer was set to 200 μm. The range of displacement of the wafer was set to two Talbot lengths, i.e. 6.4 μm and 15 μm for the 800 nm and the 1.2 μm linear grating mask, respectively. The filling factor on the phase mask is approximately 62%. The Talbot length was calculated using equation (1).

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A coherent 375 nm illumination source with an energy density of 1 mW.cm-2 was used. The energy density was controlled in real-time which allow an accurate and reliable exposure dose. After exposure, both samples with negative and positive resist were post-baked for 90 sec at 120°C. Samples with positive resist were dipped in MF-CD-26 developer for 90 sec. Samples with negative resist were dipped in AZ 726 developer for 40 sec. They were then rinsed with deionized water and dried with nitrogen gas.

1.1

Effect of the exposure dose on feature sizes

We investigated the impact of the dose exposure on linewidth, starting from an exposure dose of 50 mJ.cm-2 up to 80 mJ.cm-2, with 5 mJ.cm-2 incremental steps. The planar secondary electron (SE) scanning electron microscope (SEM) images of the pattern after development show a decrease of the linewidth with increased exposure dose (Fig. 1). The resist linewidths were extracted from the SE images and were found to decrease linearly, from 240 nm to 120 nm, as the exposure dose increases from 50 to 80 mJ.cm-2 (Fig. 2). The resist linewidth is found to change at a rate of -3.75 nm per mJ.cm-2. The linewidth of the resist can be carefully tuned controlled by adjusting the exposure dose.

Figure 1:

Secondary electron SEM images of 400 nm period linear gratings obtained in positive resist for an exposure dose of a) 50 mJ.cm-2 b) 60 mJ.cm c) 70 mJ.cm-2 and d) 80 mJ.cm-2.

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Figure 2:

Resist linewidth obtained in a 800 nm thick positive resist (Ultra i123) as a function of the exposure dose for a 800 nm period linear grating mask. Linear slope is calculated as -3.75 nm.mJ-1.cm2

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1.2

Fabrication of dashes

In order to create dash features, positive photoresist was first exposed using a 800 nm linear grating phase mask, with an exposure dose of 50 mJ.cm-2. The sample was than rotated by 90° and a second exposure was performed using a 1.2 μm linear grating phase mask. The energy of the second exposure was varied from 20 to 30 mJ.cm-2. After development, resist dashes of various dimensions were obtained on the wafer (Fig. 3). The periodicities in the two perpendicular directions, a and b were 400 nm and 600 nm respectively. As the alignment between the first and second exposure was made by eye, the dashes were not always aligned perfectly perpendicularly (e.g. in Fig. 3b). Suitable alignment marks could solve this issue.

Figure 3:

Dashes of positive resist obtained after double exposure for a dose of 50 mJ.cm-2 for the 800 nm period linear grating pattern and a) 20 mJ.cm-2 b) 22.5 mJ.cm-2 c) 25 mJ.cm-2 and d) 30 mJ.cm-2 for the 1.2 μm period linear grating

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The measured width (blue square) and length (red circle) of the dashes are plotted in Fig. 4. The width and length of the resist dashes are found to decrease with the increase of the second exposure dose (with 1.2 μm period linear grating). The variation of dimension in width is much smaller (Δwidth ~ 20 nm) than the variation of length (Δlength ~ 60 nm). From 20 to 25 mJ.cm-2, a linear decrease is seen in both width and length, from 120 nm to 100 nm in width (-4 nm/mJ-1.cm2) and from 270 nm to 220 nm in length (-10 nm/mJ.cm2). The width of the dashes is found to be much smaller than the linewidth of 240 nm that was obtained for a single illumination of 50 mJ.cm-2 (see Fig. 2), suggesting that the second illumination has significantly impacted the illumination of the resist exposed with the first linear grating mask. Between 25 and 30 mJ.cm-2, there is only a small change in dash length and width. For 35 mJ.cm-2, the resist was completely exposed so that no pattern was seen on the wafer.

Figure 4:

Length and width of the nanodashes obtained for a fixed exposure dose of 50 mJ.cm-2 for the 800 nm period linear grating mask as a function of the exposure dose for the 1.2 μm period linear grating mask.

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1.3

Modelling of the aerial intensity distribution and resist development

Modelling was performed in order to understand the results obtained, using two different linear grating phase masks and rotating the sample by 90° between each exposure. A 800 nm period and a 1.2 μm period grating phase mask that have a filling factor of 62% were used in the modelling to match the gratings used in our experiments. Fig. 5a and 5b display a normalised aerial pattern, which represents the energy of the light below the mask integrated over one Talbot length at a distance of 200 μm from the mask, for a 800 nm and a 1.2 μm period linear grating mask. Fig. 5c and 5d show corresponding cross-sections through the intensity distributions across the gratings and highlight that the intensity of the two alternating families of peaks are not equal. The 1st family is slightly more intense than the 2nd in the case of the 800 nm period linear grating while the opposite is found in the case of the 1.2 μm period linear grating. In both cases, an intensity background equivalent to ~0.2 is present. This intensity background will have an impact on the illumination of the entire resist. This explains why an increase of energy on the 1.2 μm period linear grating led to a decrease in the width of the dashes. It also explains why a dose of 50 mJ.cm-2 for the first exposure produces dashes of width between 100 to 120 nm if followed by a second exposure, whilst a 240 nm grating linewidth is obtained for a single exposure.

Figure 5:

Aerial intensity image of the Talbot carpet integrated over one Talbot length for a) a 800 nm period linear grating phase mask b) a 1.2 μm period linear grating mask. Normalized intensity of the energy obtained below the mask at a distance of 200 μm for c) a 800 nm period d) 1.2 μm linear grating mask.

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Combining both exposures, a new aerial intensity distribution was obtained. The exposure dose of the 800 nm period linear grating was fixed at 170 mJ.cm-2 whilst the exposure dose of the 1.2 μm period linear grating was varied, with values of 30 mJ.cm-2 and 70 mJ.cm-2 (Fig.6a and 6b). The results from the development of the resist after exposure shows that length of the dashes will be reduced substantially by increasing the energy while the width change is relatively small (about 7 nm). The asymmetry of the dashes, seen especially in Fig. 6c can be attributed to the variation of relative intensity between the primary and the secondary pattern. A more appropriate mask filling factor could be designed in order to obtain the same energy for both the primary and secondary pattern. This effect was not seen in our experiments.

Figure 6:

Aerial intensity distribution obtained for the combination of a 800 nm and 1.2 μm linear grating mask rotated by 90° with respective exposure doses of a) 170/30 mJ.cm-2 and b) 170/70 mJ.cm-2. Corresponding resist patterns expected after development for a double exposure for doses: c) 170/30 mJ.cm-2 and d) 170/70 mJ.cm-2.

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1.4

Creation of a lift-off profile

The 250 nm thick resist was used as an etch mask and transferred into the underlying HSQ layer using a plasma dry etch step in order to create an undercut lift-off profile. CHF3 plasma was used with the following parameters: a pressure of 8 mTorr, an RF power of 50W, an ICP power of 300W and a CHF3 flow of 25 sccm. The temperature was set to 20°C and 1 min etch, 1 min cooling steps were introduced in order to maintain the sample temperature. The etching rates for this recipe were measured to be 45 nm.min-1 for the resist and the BARC and 48 nm.min-1 for the HSQ. The samples were etched for 5 min to allow the etching of 90 nm of the BARC layer and 120 nm of HSQ. The planar SE image taken after the 5 min etching steps highlight the dimensions of the dashes were not fundamentally modified by the etching step (Fig. 7a). After this plasma etch step, the sample was dipped in a solution of Buffered Oxide Etch (BOE) 100:1 at 20°C for 35 sec. The SE cross-section image in Fig. 7b displays the profile of the obtained structure after the CHF3 and the BOE steps and shows a clear undercut can has been obtained.

Figure 7:

a) Dashes after CHF3 etching b) cross section SE image of a dash after BOE 100:1 for 35 sec showing the undercut profile.

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A 70 nm thick metallic layer (Ti(5 nm)/Au(65 nm)) was deposited by e-beam evaporation on each pattern. The samples were dipped in BOE 5:1 to perform the lift-off. Figure 8 displays the SE images taken after the lift-off. A metallic fishnet with period of 400nm and 600 nm, with aperture of 120 nm in width and 290 nm in length were obtained for 50/20 mJ.cm-2 combination and 105 nm in width and 210 nm in length for 50/25 mJ.cm-2 combination.

Figure 8:

Ti (5 nm)/Au(6 0nm) thick metallic ‘fishnet’ like structure obtained after lift-off for a dose of 50 mJ.cm-2 for the 800 nm grating exposure and a dose of a) 20 mJ.cm-2 b) 25 mJ.cm-2 for the second 1.2 μm grating exposure.

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1.5

Fabrication of elliptical holes in resist

A similar process was performed using a 350 nm thick negative resist (AZ 15 NXT diluted with EBR about 7:12 by weight). Fig. 9 displays the secondary electron images of the resist pattern obtained for fixed exposure dose of 120 mJ.cm-2 for the 800 nm period linear grating mask and a varied exposure dose of 35 to 50 mJ.cm-2 for the 1.2 μm period linear grating mask. Elliptical holes were obtained in the resist. The width and length of the elliptical holes decreased with the increase of the 1.2 μm period linear grating exposure dose.

Figure 9:

Elliptical holes obtained in a 350 nm thick negative resist after double exposure for a dose of 120 mJ.cm-2 for the 800 nm linear grating pattern and a) 35 mJ.cm-2 b) 40 mJ.cm-2 c) 45 mJ.cm-2 and d) 50 mJ.cm-2 for the 1.2 μm linear grating pitch

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The measured width (blue square) and length (red circle) of the holes are summarized and plotted in Fig. 10. The width and length of the holes are found to decrease with the increase of the second exposure dose (with 1.2 μm period linear grating) in a similar fashion as shown previously for the resist dashes.

Figure 10:

Length and width of the elliptical holes obtained for a fixed exposure dose of 120 mJ.cm-2 for the 800 nm period linear grating mask as a function of the dose for the 1.2 μm period linear grating mask.

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CONCLUSION

We have demonstrated that displacement Talbot lithography can be used to fabricate arrays of dashes and fishnet type structures with the dimensions that are required to fabricate negative-index metamaterials in the NIR range. The simplicity, high throughput, and low cost of such techniques combined with its high tunability range offers an interesting alternative to e-beam lithography or nanoimprint lithography techniques. In the future, we aim to further investigate the range of dimension that can be successfully fabricated and aim to demonstrate a lift-off process with the negative resist to obtain metallic or multilayer material dashes. We believe these techniques could pave the way to the fabrication of optical metamaterials and plasmonic metasurfaces in the near infrared and in the visible range in the near future.

AUTHOR INFORMATION & ACKNOWLEDGEMENTS

The manuscript was written through contributions of all authors. / All authors have given approval to the final version of the manuscript.

Financial support is acknowledged from the EPSRC, UK via Grant No. EP/M015181/1, “Manufacturing nano-GaN”. The data associated with this research are available at https://doi.org/10.15125/BATH-00363 or from the corresponding author.

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© (2017) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
E. D. Le Boulbar, P. J. P. Chausse, S. Lis, P. A. Shields, "Displacement Talbot lithography: an alternative technique to fabricate nanostructured metamaterials", Proc. SPIE 10248, Nanotechnology VIII, 102480Q (8 June 2017); doi: 10.1117/12.2265774; https://doi.org/10.1117/12.2265774
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