Dynamics of fast rotating molecules: microscopic approach

Sergei V. Petrov; Sergei E. Lokshtanov

doi:10.1117/12.375405

25 January 2000 Dynamics of fast rotating molecules: microscopic approach

Sergei V. Petrov, Sergei E. Lokshtanov

Proceedings Volume 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy; (2000) https://doi.org/10.1117/12.375405
Event: 13th Symposium and School on High-Resolution Molecular Spectroscopy, 1999, Tomsk, Russian Federation

Abstract

One of the possible ways to analyze rotational dynamics of molecules in case when the ro-vibrational interaction can not be considered as a small one is discussed in this paper. In the method proposed the most part of the ro-vibrational interaction is taken into account in zero-order approximation. Applied to the number of real molecular ro- vibrational problems, this approach has been proved to be a sufficiently powerful tool for rotational dynamics qualitative analysis and then for revealing rotational multiplet structure. It also can be considered as a base for quantum rotational energy levels calculations.

Citation Download Citation

Sergei V. Petrov and Sergei E. Lokshtanov "Dynamics of fast rotating molecules: microscopic approach", Proc. SPIE 4063, 13th Symposium and School on High-Resolution Molecular Spectroscopy, (25 January 2000); https://doi.org/10.1117/12.375405

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